2024
(120) Cosio, M. N.; Lee, S. R.; Lai, Q.; Bhuvanesh, N.; Zhou, J.; Ozerov, O. V. Dimeric Rh Complexes Supported by a Bridging Phosphido/Bis(Phosphine) PPP Ligand, Organometallics 2024, Accepted.
(119) Leong, D. W.; Shao, Y.; Zhen, N.; Bhuvanesh, N.; Ozerov, O. V. A Bis(PCN) Palladium Pincer Complex with a Remarkably Planar 2,5-Diarylpyrazine Core, Dalton Trans. 2024, 53, 6520-6523.
2023
(118) Nguyen, V. T.; Lai, Q.; Witayapaisitsan, N.; Bhuvanesh, N.; Surawatanawong. P.; Ozerov, O. V. Migration of Hydride, Methyl, and Chloride Ligands between Al and M in (PAlP)M Pincer Complexes (M = Rh or Ir), Organometallics 2023, 42, 3120-3129.
(117) Davidson, J. J.; Gunther, S. O.; Leong, D. W.; Ozerov, O. V.; Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants, Dalton Trans. 2023, 52, 16027-16031.
2022
(116) Talosig, A. R.; Cosio, M. N.; Morse, B.; Nguyen V. T.; Kosanovich, A. J.; Pell, C. J.; Li, C.; Bhuvanesh, N.; Zhou, J.; Larsen, A. S.; Ozerov, O. V.; Johnson, M. W. Distinct modes of Si-H binding to Rh in complexes of a phosphine-diarylamido-silane (SiNP) pincer ligand, Dalton Trans. 2022, 51, 14150-14155.
(115) Vidlak, J. F.; Cosio, M. N.; Sriramaneni, N. K.; Bhuvanesh, N.; Ozerov, O. V.; Johnson, M. W. Synthesis of pyrrole-based PSiP pincer ligands and their palladium, rhodium, and platinum complexes, Dalton Trans. 2022, 51, 7797-7803.
(114) Gunther, S. O.; Lee, C.-I; Song, E.; Bhuvanesh, N.; Ozerov, O. V. Isolable fluorinated triphenylmethyl cation salts of [HCB11Cl11]-: demonstration of remarkable hydride affinity, Chem. Sci. 2022, 13, 4972-4976.
2021
(113) Cao, Y.; Shih, W.-C.; Bhuvanesh, N.; Zhou, J.; Ozerov, O. V. Cooperative C-H activation of pyridine by PBP complexes of Rh and Ir can lead to bridging 2-pyridyls with different connectivity to the B-M unit, Chem. Sci. 2021, 12, 14167-14173. See also the correction.
(112) Lai, Q.; Bhuvanesh, N.; Zhou, J.; Ozerov, O. V. Formation of an Ag → Al dative bond is avoided in reactions of an alane/tris(phosphine) ligand with monovalent silver, Dalton Trans. 2021, 50, 5776-5778.
(111) Hung, M.-U.; Press, L.; Bhuvanesh, N.; Ozerov, O. V. Examination of a Series of Ir and Rh PXL Pincer Complexes as (Pre)Catalysts for Aromatic C-H Borylation, Organometallics 2021, 40, 1004-1013.
(110) Ramírez-Contreras, R.; Cosio, M. N.; Park, S.; Bhuvanesh, N.; Ozerov, O. V. Arene Coordination Induces Migration of a Hydride to a Ru-Bound Carbene of a Pincer Ligand, J. Organomet. Chem. 2021, 938, 121747.
(109) Gunther, S. O.; Kosanovich, A. J.; Cao, Y.; Bhuvanesh, N.; Ozerov, O. V. Nucleopincers? Rhodium Complexes of Pyrimidine-centered PNP Pincer Ligands Derived from Nitrogenous Nucleobases Uracil and Thymine, Z. anorg. allg. Chem. 2021, 647, 1421-1428. Published as part of a special issue on pincer ligands.
(108) Gunther, S. O.; Lai, Q.; Senecal, T.; Huacuja, R.; Bremer, S.; Pearson, D. M.; Demott, J. C.; Bhuvanesh, N.; Ozerov, O. V.; Klosin, J. Highly Efficient Carborane-Based Activators for Molecular Olefin Polymerization Catalysts, ACS Catal. 2021, 11, 3335-3342.
(107) Lai, Q.; Ozerov, O. V. Dehydrogenative Diboration of Alkynes Catalyzed by Ir/CO/tBuNC System, J. Organomet. Chem. 2021, 931, 121614.
2020
(106) Lai, Q.; Bhuvanesh, N.; Ozerov, O. V. Unexpected B/Al Transelementation Within a Rh Pincer Complex, J. Am. Chem. Soc. 2020, 142, 20920-20923.
(105) Lai, Q.; Cosio, M. N.; Ozerov, O. V. Ni Complexes of an Alane/Tris(phosphine) Ligand Built Around a Strongly Lewis Acidic Tris(N-pyrrolyl)aluminum, Chem. Commun. 2020, 56, 14845-14848.
(104) Cao, Y.; Shih, W.-C.; Bhuvanesh, N. S.; Ozerov, O. V. Reversible Addition of Ethylene to a Pincer-Based Boryl-Iridium Unit with the Formation of a Bridging Ethylidene, Chem. Sci. 2020, 11, 10998-11002.
(103) Yu, C.-H.; Zhu, C.; Ji, X.; Hu, W.; Xie, H.; Bhuvanesh, N. S.; Fang, L.; Ozerov, O. V. Palladium Bis-Pincer Complexes with Controlled Rigidity and Inter-Metal Distance, Inorg. Chem. Front. 2020, 7, 4357-4366.
(102) Foley, B. J.; Bhuvanesh, N. S.; Zhou J.; Ozerov, O. V. Combined Experimental and Computational Studies of the Mechanism of Dehydrogenative Borylation of Terminal Alkynes (DHBTA) Catalyzed by PNP Complexes of Iridium, ACS Catal. 2020, 10, 9824-9836.
(101) Yu, C.-H.; Yang, X.; Ji, X.; Wang, C-H.; Lai, Q.; Bhuvanesh, N.; Ozerov, O. V. Redox Communication between Two Diarylamido/Bis(phosphine) (PNP)M Moieties Bridged by Ynediyl Linkers (M = NI, Pd, Pt), Inorg. Chem. 2020, 59, 10153-10162.
(100) Foley, B. J.; Ozerov, O. V. Air- and Water-Tolerant (PNP)Ir Precatalyst for the Dehydrogenative Borylation of Terminal Alkynes, Organometallics 2020, 39, 2352-2355.
(99) Foley, B. J.; Palit, C. M.; Bhuvanesh, N.; Zhou, J.; Ozerov, O. V. Concerted aryl-sulfur reductive elimination from PNP pincer-supported Co(III) and subsequent Co(I)/Co(III) comproportionation, Chem. Sci., 2020, 11, 6075-6084.
(98) Pell, C. J.; Ozerov, O. V. Synthesis and Rh-catalyzed reductive cyclization of 1,6-enynes and 1,6-diynes containing alkynylboronate termini, J. Organomet. Chem. 2020, 912, 121143.
2019
(97) Cao, Y.; Shih, W.-C.; Ozerov, O. V. Addition of O-H, N-H and F-H Bonds across a Boryl-Iridium Unit, Organometallics 2019, 38, 4076-4081.
(96) Cao, Y.; Shih, W.-C.; Bhuvanesh, N.; Ozerov, O. V. Silver Halide Complexes of a Borane/Bis(Phosphine) Ligand, Dalton Trans. 2019, 48, 9959-9961.
(95) Kosanovich, A. J.; Shih, W.-C.; Ozerov, O. V. Synthesis and characterization of unsaturated Manganese(I) and Rhenium(I) dicarbonyl complexes supported by an anionic PNP pincer, J. Organomet. Chem. 2019, 897, 1-6.
2018
(94) Zhang, J.; Foley, B. J.; Bhuvanesh, N.; Zhou, J.; Janzen, D. E.; Whited, M. T.; Ozerov, O. V. Synthesis and Reactivity of Pincer-Type Cobalt Silyl and Silylene Complexes, Organometallics 2018, 37, 3956-3962.
(93) Foley, B. J.; Palit, C. M.; Timpa, S. D.; Ozerov, O. V. Synthesis of (POCOP)Co(Ph)(X) Pincer Complexes and Observation of Aryl-Aryl Reductive Elimination Involving the Pincer Aryl, Organometallics 2018, 37, 3803-3812.
(92) Kosanovich, A. J.; Jordan, A. M.; Bhuvanesh, N.; Ozerov, O. V. Synthesis and Characterization of Rhodium, Iridium, and Palladium complexes of a Diarylamido-Based PNSb Pincer Ligand, Dalton Trans. 2018, 47, 11619-11624.
(91) Kosanovich, A. J.; Komatsu, C. H.; Bhuvanesh, N.; Pérez, L. M.; Ozerov, O. V. Dearomatization of the PCP Pincer Ligand in a Re(V) Oxo Complex, Chem. Eur. J. 2018, 24, 13754-13757.
(90) Kosanovich, A. J.; Shih, W.-C.; Ozerov, O. V. Irreversible Hydrolysis of PCP-Supported Rhenium(V) Acetates, Inorg. Chem. 2018, I, 545-547.
(89) Zhou, J.; Lee, C.-I; Ozerov, O. V. Computational Study of the Mechanism of Dehydrogenative Borylation of Terminal Alkynes by SiNN Iridium Complexes, ACS Catal. 2018, 8, 536-545.
2017
(88) Shih, W.-C.; Ozerov, O. V. Selective ortho-C–H Activation of Pyridines Directed by the Lewis Acidic Boron of PBP Pincer Iridium Complexes, J. Am. Chem. Soc. 2017, 139, 17297-17300.
(87) Zabula, A. V.; Qiao, Y.; Kosanovich, A. J.; Cheisson, T.; Manor, B. C.; Carroll, P. J.; Ozerov, O. V.; Schelter, E. J. Structure, Electronics, and Reactivity of Ce(PNP) Complexes, Chem. Eur. J. 2017, 23, 19723-17934.
(86) Pell, C. J.; Shih, W.-C.; Gatard, S.; Ozerov, O. V. Formation of (PNP) Rh complexes containing covalent rhodium-zinc bonds in studies of potential Rh-catalysed Negishi coupling, Chem. Commun. 2017, 53, 6456-6459.
(85) Shih, W.-C.; Gu, W.; MacInnis, M. C.; Herbert, D. E.; Ozerov, O. V. Boryl/Borane Interconversion and Diversity of Binding Modes of Oxygenous Ligands in PBP Pincer Complexes of Rhodium, Organometallics 2017, 36, 1718-1726.
(84) Pell, C. J.; Zhu, Y.; Huacuja, R.; Herbert, D. E.; Hughes, R.; Ozerov, O. V. Fluorocarbene, Fluoroolefin, and Fluorocarbyne Complexes of Rh, Chem. Sci. 2017, 8, 3178-3186.
(83) Shih, W.-C.; Ozerov, O. V. Synthesis and Characterization of PBP Pincer Iridium Complexes and Their Application in Alkane Transfer Dehydrogenation, Organometallics 2017, 36, 228-233.
(82) Kosanovich, A. J.; Press, L. P.; Ozerov, O. V. Boryl Transfer Reactivity of a POCOP-Supported Ir-diboryl: Reduction of CO2 to CO and Borylation of Other Small Molecules, J. Organomet. Chem. 2017, 23, 19-24.
2016
(81) MacInnis, M. C.; DeMott, J. C.; Zolnhofer, E. M.; Zhou, J. Meyer, K.; Hughes, R. P.; Ozerov, O. V. Cationic Two-Coordinate Complexes of Pd(I) and Pt(I) Have Longer Metal-Ligand Bonds Than Their Neutral Counterparts, Chem 2016, 1, 902-920.
(80) Kosanovich, A. J.; Shih, W.-C.; Ramírez-Contreras, R.; Ozerov, O. V. N-H Cleavage as a Route to New Pincer Complexes of High-Valent Rhenium, Dalton Trans. 2016, 45, 18532-18540.
(79) Press, L. P.; Kosanovich, A. J.; McCulloch, B. J.; Ozerov, O. V. High-Turnover Aromatic C-H Borylation Catalyzed by POCOP-type Pincer Complexes of Iridium, J. Am. Chem. Soc. 2016, 138, 9487-9497.
(78) Shih, W.-C.; Gu, W.; MacInnis, M. C.; Timpa, S. D.; Bhuvanesh, N.; Zhou, J.; Ozerov, O. V. Facile Insertion of Rh and Ir into a Boron–Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes, J. Am. Chem. Soc. 2016, 138, 2086-2089.
(77) Kosanovich, A. J.; Reibenspies, J. H.; Ozerov, O. V. Complexes of High-Valent Rhenium Supported by the PCP Pincer, Organometallics 2016, 35, 513-519.
2015
(76) Shih, W.-C.; Ozerov, O. V. One Pot Synthesis of 1,3-Bis(phosphinomethyl)arene PCP/PNP Pincer Ligands and their Nickel Complexes, Organometallics 2015, 34, 4591-4597.
(75) Lee, C.-I; Shih, W.-C.; Zhou, J.; Reibenspies, J. H.; Ozerov, O. V. Synthesis of Triborylalkenes by Ir-Catalyzed Tandem C-H Borylation and Diboration, Angew. Chem., Int. Ed. 2015, 54, 14003-14007. See highlights in C&EN News.
(74) DeMott, J. C.; Dekarske, J. R.; McCulloch, B. J.; Ozerov, O. V. Cyclometallation of the NNN Pincer Ligand in Complexes of Platinum, Inorg. Chem. Front. 2015, 2, 912-916.
(73) Lee, C.-I; DeMott, J. C.; Pell, C. J.; Christopher, A.; Zhou, J.; Bhuvanesh, N.; Ozerov, O. V. Ligand Survey Results in Identification of PNP Pincer Complexes of Iridium as Long-lived and Chemoselective Catalysts for Dehydrogenative Borylation of Terminal Alkynes, Chem. Sci. 2015, 6, 6572-6582.
(72) DeMott, J. C.; Gu, W.; McCulloch, B. J.; Herbert, D. E.; Goshert, M. D.; Walensky, J. R.; Zhou, J.; Ozerov, O. V. Silyl-Silylene Interplay in Cationic PSiP Pincer Complexes of Platinum, Organometallics 2015, 34, 3930-3933.
(71) Press, L. P.; McCulloch, B. J.; Gu, W.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Triflyloxy-Substituted Carboranes as Useful Weakly Coordinating Anions, Chem. Commun. 2015, 51, 14034-14037.
(70) Pell, C. J.; Ozerov, O. V. Catalytic Dehydrogenative Borylation of Terminal Alkynes by POCOP-Supported Palladium Complexes, Inorg. Chem. Front. 2015, 2, 720-724.
(69) Ramírez-Contreras, R.; Bhuvanesh, N.; Ozerov, O. V. Cycloaddition and C-H Activation Reactions of a Tantalum Alkylidyne, Organometallics 2015, 34, 1143-1146.
(68) Lee, C.-I; Hirscher, N. A.; Zhou, J.; Bhuvanesh, N.; Ozerov, O. V. Adaptability of the SiNN Pincer Ligand in Iridium and Rhodium Complexes Relevant to Borylation Catalysis, Organometallics 2015, 34, 3099-3102. Graphic chosen for the cover. See story.
(67) Davidson, J. J.; DeMott, J. C.; Douvris, C.; Fafard, C. M.; Bhuvanesh, N.; Chen, C.-H.; Herbert, D. E.; Lee, C.-I; McCulloch, B. J.; Foxman, B. M.; Ozerov, O. V. Comparison of the Electronic Properties of Diarylamido-Based PNZ Pincer Ligands: Redox Activity at the Ligand and Donor Ability Towards the Metal, Inorg. Chem. 2015, 54, 2916-2935.
2014
(66) Timpa, S. D.; Pell, C. J.; Ozerov, O. V. A Well-Defined (POCOP)Rh Catalyst for the Coupling of Aryl Halides with Thiols, J. Am. Chem. Soc. 2014, 136, 14772-14779.
(65) Timpa, S. D.; Zhou, J.; Bhuvanesh, N.; Ozerov, O. V. Potential Carbon-Fluorine Reductive Elimination from Pincer-Supported Rh(III) and Dominating Side Reactions: Theoretical and Experimental Examination, Organometallics 2014, 33, 6210-6217.
(64) Timpa, S. D.; Pell, C. J.; Zhou, J.; Ozerov, O. V. Fate of Aryl/Amido Complexes of Rh(III) Supported by a POCOP Pincer Ligand: C-N Reductive Elimination, beta-Hydrogen Elimination, and Relevance to Catalysis, Organometallics 2014, 33, 5254-5262.
(63) Pell, C. J.; Ozerov, O. V. A Series of Pincer-Ligated Rhodium Complexes as Catalysts for the Dimerization of Terminal Alkynes, ACS Catal. 2014, 4, 3470-3480.
(62) Davidson, J. J.; Nagaraja,P C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Palladium Complexes of a New Phosphine-Amido-Siloxide Pincer Ligand with Variable Degrees of Protonation, Inorg. Chim. Acta. 2014, 422, 70-77.
(61) Palit, C. M.; Graham,U D. J.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Reduction of CO2 to Free CO by a Pd(I)-Pd(I) Dimer, Chem. Commun. 2014, 50, 12840-12842.
2013
(60) Ramírez-Contreras, R.; Bhuvanesh, N.; Zhou,P J.; Ozerov, O. V. Synthesis of a Silylium Zwitterion, Angew. Chem., Int. Ed. 2013, 52, 10313-10315.
(59) Smith, D. E.; Herbert, D. E.; Walensky, J. R.; Ozerov, O. V. Monomeric Rh(II) Complexes Supported by a Diarylamido/Bis(Phosphine) PNP Pincer Ligand and Their Reactivity Towards Dihydrogen, Organometallics 2013, 32, 2050-2058.
(58) Lee, C.-I; Zhou, J.; Ozerov, O. V. Catalytic Dehydrogenative Borylation of Terminal Alkynes by a SiNN Pincer Complex of Iridium, J. Am. Chem. Soc. 2013, 135, 3560-3566.
(57) Walensky, J. R.; Fafard, C. M.; Guo, C.; Brammell, C. M.; Foxman, B. M.; Hall, M. B.; Ozerov, O. V. Understanding Pd-Pd Bond Length Variation in (PNP)Pd-Pd(PNP) Dimers, Inorg. Chem. 2013, 52, 2317-2322.
(56) DeMott, J. C.; Bhuvanesh, N.; Ozerov, O.V. Frustrated Lewis Pair-Like Splitting of Aromatic C-H Bonds and Abstraction of Halogen Atoms by a Cationic [(FPNP)Pt]+ Species, Chem. Sci. 2013, 4, 642-649.
2012
(55) Kwan, M.-L.; Conry, S. J.; Carfagna, C. S.; Press, L. P.; Ozerov, O. V.; Hoffman, N. W.; Sykora, R. E. {2,6-Bis[2,6-diisopropylphosphanyl)-oxy]-4-fluorophenyl-κ3P,C1,P'}(1H-pyrazole-κN2)nickel(II)hexafluorophosphate, Acta Cryst. 2012, E68, m1282-m1283.
(54) Ramírez-Contreras, R.; Ozerov, O. V. Convenient C-Alkylation of the [HCB11Cl11]- Carborane Anion, Dalton Trans. 2012, 41, 7842-7844.
(53) Herbert, D. E.; Miller, A. D.; Ozerov, O. V. Phosphorus(III) Cations Supported by a PNP Pincer Ligand and Sub-Stoichiometric Generation of P4 from Thermolysis of a Nickel Insertion, Chem. Eur. J. 2012, 18, 7696-7704.
(52) Zhu, Y.; Smith, D. A.; Herbert, D. E.; Gatard, S.; Ozerov, O. V. C-H and C-O Oxidative Addition in Reactions of Aryl Carboxylate with a PNP Pincer-Ligated Rh(I) Fragment, Chem. Commun. 2012, 48, 218-220.
2011
(51) Herbert, D. E.; Ozerov, O. V. Binuclear Palladium Complexes Supported by Bridged Pincer Ligands, Organometallics 2011, 30, 6641-6654.
(50) Smith, D. A.; Ozerov, O. V. Early-Late Heterobimetallic Rh-Ti and Rh-Zr Complexes via Addition of Early Metal Chlorides to Mono- and Divalent Rhodium, Chem. Commun. 2011, 47, 10779-10781.
(49) DeMott, J. C.; Surawatanawong, P.; Barnett, S. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Experimental and Computational Exploration of the Dynamic Behavior of (PNP)BF2, a Boron Compound Supported by an Amido/Bis(Phosphine) Pincer Ligand, Dalton Trans. 2011, 40, 11562-11570.
(48) Zhu, Y.; Chen, C.-H.; Fafard, C. M.; Foxman, B. M.; Ozerov, O. V. Net Heterolytic Cleavage of B-H and B-B Bonds Across the N-Pd Bond in a Cationic (PNP)Pd Fragment, Inorg. Chem. 2011, 50, 7980-7987.
(47) Brammell, C. M.; Pelton, E. J.; Chen, C.-H.; Yakovenko, A. A.; Weng, W.; Foxman, B. M.; Ozerov, O. V. Hafnium Alkyl Complexes of the Anionic PNP Pincer Ligand and Possible Alkylidene Formation, J. Organomet. Chem. 2011, 696, 4132-4137.
(46) Surawatanawong, P.; Ozerov, O. V. Computational Studies of Reactions of Insertion of Rh(I) and Ir(I) into N-H, N-CH3, and NCH2-H Bonds of the Diarylamine-Based PNP Pincer Ligands, Organometallics 2011, 30, 2972-2979.
(45) Puri, M.; Gatard, S.; Smith, D. A.; Ozerov, O. V. Competition Studies of Oxidative Addition of Aryl Halides to the (PNP)Rh Fragment, Organometallics 2011, 30, 2472-2482.
(44) Timpa, S. D.; Fafard, C. M.; Herbert, D. E.; Ozerov, O. V. Catalysis of Kumada-Tamao-Corriu Coupling by a (POCOP)Rh Pincer Complex, Dalton Trans. 2011, 40, 5426-5429.
(43) Gu, W.; Ozerov, O. V. Exhaustive Chlorination of [B12H12]2- without Chlorine Gas and the Use of [B12Cl12]2- as Supporting Anion in Catalytic Hydrodefluorination of Aliphatic C-F Bonds, Inorg. Chem. 2011, 50, 2726-2728.
(42) Huacuja, R.; Graham, D. J.; Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Herbert, D. E.; Alliger, G.; Thomas, C. M.; Ozerov, O. V. Reactivity of a Pd(I)-Pd(I) Dimer with O2: Monohapto Pd Superoxide and Dipalladium Peroxide in Equilibrium, J. Am. Chem. Soc. 2011, 133, 3820-3823.
(41) Hollas, A. M.; Gu, W.; Bhuvanesh, N.; Ozerov, O. V. Synthesis and Characterization of Pd Complexes of a Carbazolyl/Bis(Imine) NNN Pincer Ligand, Inorg. Chem. 2011, 50, 3673-3679.
(40) Gusev, D. G.; Ozerov, O. V. Calculated Hydride and Fluoride Affinities of a Series of Carbenium and Silylium Cations in the Gas Phase and C6H5Cl Solution, Chem. Eur. J. 2011, 17, 634-640.
2010
(39) Huacuja, R.; Herbert, D. E.; Fafard, C. M.; Ozerov, O. V. A Terminal Palladium Fluoride Complex Supported by an Anionic PNP Pincer Ligand, J. Fluor. Chem. 2010, 131, 1257-1261 (special issue in honor of R. P. Hughes).
(38) Bacciu, D.; Chen, C.-H.; Surawatanawong, P.; Foxman, B. M.; Ozerov, O. V. High-Spin Manganese(II) Complexes of an Amido/Bis(Phosphine) PNP Ligand, Inorg. Chem. 2010, 49, 5328-5334.
(37) Gu, W.; McCulloch, B. J.; Reibenspies, J. H.; Ozerov, O. V. Improved Methods for the Halogenation of the [HCB11 H11]− Anion, Chem. Commun. 2010, 46, 2820-2822. See also the addition/correction online.
(36) Douvris, C.; Nagaraja, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Hydrodefluorination and Other Hydrodehalogenation of Aliphatic Carbon-Halogen Bonds Using Silylium Catalysis, J. Am. Chem. Soc. 2010, 132, 4946-4953.
(35) Gregor, L. C.; Chen, C.-H.; Fafard, C. M.; Fan, L.; Guo, C.; Foxman, B. M.; Gusev, D. G.; Ozerov, O. V. Heterolytic splitting of H-X bonds at a cationic (PNP)Pd center, Dalton Trans. 2010, 39, 3195-3202.
2009
(34) Radosevich, A. T.; Melnick, J. G.; Stoian, S. A.; Bacciu, D.; Chen, C-H.; Foxman, B. M.; Ozerov, O. V.; Nocera, D. G. Ligand Reactivity in PNP-Complexes of Mn(CO)3 and Re(CO)3, Inorg. Chem. 2009, 48, 9214-9221.
(33) Gu, W.; Haneline, M. R.; Douvris, C.; Ozerov, O. V. Carbon−Carbon Coupling of C(sp3)−F Bonds Using Alumenium Catalysis, J. Am. Chem. Soc. 2009, 131, 11203-11212.
(32) Whited, M. T.; Zhu, Y.; Timpa, S. D.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V.; Grubbs, R. H. Probing the C−H Activation of Linear and Cyclic Ethers at (PNP)Ir, Organometallics 2009, 28, 4560-4570.
(31) Ozerov, O. V., Oxidative Addition of Water to Transition Metal Complexes, Chem. Soc. Rev. 2009, 38, 83-88.
2008
(30) Sircoglou, M.; Bontemps, S.; Bouhadir, G.; Saffon, N.; Miqueu, K.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou, D. Group 10 and 11 Metal Boratranes (Ni, Pd, Pt, CuCl, AgCl, AuCl and Au+) Derived from a Triphosphine–Borane, J. Am. Chem. Soc. 2008, 130, 16729-16738.
(29) Gatard, S.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Oxidative Addition Reactions of Silyl Halides with the (PNP)Rh fragment, Organometallics 2008, 27, 6257-6263.
(28) Douvris, C.; Ozerov, O. V. Hydrodefluorination of Perfluoroalkyl Groups Using Silylium-Carborane Catalysts, Science 2008, 321, 1188-1190. Please see the press coverage summary here.
(27) Masuda, J. D.; Jantunen, K. C.; Ozerov, O. V.; Noonan, K. J. T.; Gates, D. P.; Scott, B. L.; Kiplinger, J. L. A Lanthanide Phosphinidene Complex: Synthesis, Structure, and Phospha-Wittig Reactivity, J. Am. Chem. Soc. 2008, 130, 2408-2409.
See a highlight in the February 11th, 2008 issue of Chemical and Engineering News 2008, 86(6), 46.
(26) Bontemps, S.; Bouhadir, G.; Gu, W.; Mercy, M.; Chen, C.-H.; Foxman, B. M.; Maron, L.; Ozerov, O. V.; Bourissou, D. Metallaboratranes Derived from a Triphosphanyl-Borane: Intrinsic C3 Symmetry Supported by a Z-Type Ligand, Angew. Chem. Int. Ed. 2008, 47, 1481-1484.
2007
Book chapter: Ozerov, O. V. Rigid PNP Pincer Ligands and their Transition Metal Complexes, in The Chemistry of Pincer Compounds (ISBN-10: 0-444-53138-6), Elsevier, 2007.
(25) Zhu, Y.: Fan, L.; Chen, C.-H.; Finnell, S. R.; Foxman, B. M.; Ozerov, O. V. C-H Oxidative Addition to a (PNP)Ir Center and Ligand-Induced Reversal of Benzyl/Aryl Selectivity, Organometallics 2007, 26, 6701-6703.
(24) Gatard, S.; Guo, C.; Foxman, B. M.; Ozerov, O. V. Thioether, Dinitrogen, and Olefin Complexes of (PNP)Rh: Kinetics and Thermodynamics of Exchange and Oxidative Addition Reactions, Organometallics 2007, 26, 6066-6075.
(23) Fafard, C. M.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Covalent Palladium-Zinc Bonds and Their Reactivity, Chem. Commun. 2007, 4465-4467.
(22) Gerber, L. C. H.; Watson, L. A.; Parkin, S.; Weng, W.; Foxman, B. M.; Ozerov, O. V. A Bis(methylidene) Complex of Tantalum Supported by a PNP Ligand, Organometallics 2007, 26, 4866-4868.
(21) Fafard, C. M.; Adhikari, D.; Foxman, B. M.; Mindiola, D. J.; Ozerov, O. V. Addition of Ammonia, Water, and Dihydrogen Across a Single Pd-Pd Bond, J. Am. Chem. Soc. 2007, 129, 10318-10319.
(20) Weng, W.; Chen, C.-H.; Foxman, B. M.; Ozerov, O. V. Palladium Complexes of a P2C= Ligand Containing a Central Carbene Moiety, Organometallics 2007, 26, 3315-3320.
(19) DeMott, J. C.; Basuli, F.; Kilgore, U. J.; Foxman, B. M.; Huffman, J. C.; Ozerov, O. V.; Mindiola, D. J. Silver(I) and Thallium(I) Complexes of a PNP Ligand and Their Utility as PNP Transfer Reagents, Inorg. Chem. 2007, 46, 6271-6276.
(18) DeMott, J. C.; Guo, C.; Foxman, B. M.; Yandulov, D. V.; Ozerov, O. V. Five-coordinate aluminum complexes of a PNP ligand, Mendeleev Commun. 2007, 17, 63-65. (invited contribution to the Higher Chemical College issue)
(17) Fafard, C. M.; Ozerov, O. V. Retardation of beta-Hydrogen Elimination in PNP Pincer Complexes of Pd, Inorg. Chim. Acta. 2007, 360, 286-292. (invited contribution for the Next Generation issue)
(16) Ozerov, O. V.; Moura, C. P.; Hoffman, N. W. Experiments in Thermodynamics and Kinetics of Phosphine Substitution in (p-Cymene)RuCl2(PR3), J. Chem. Ed. 2007, 84, 489.
2006
(15) Weng, W.; Parkin, S.; Ozerov, O. V. Double C-H Activation Results in Ru Complexes of a Neutral PCP Ligand With a Central Carbene Moiety, Organometallics 2006, 25, 5345-5354.
(14) Ozerov, O. V.; Guo, C.; Foxman, B. M. Missing Link: PCP Pincer Ligands Containing P-N Bonds And Their Pd Complexes, J. Organomet. Chem. 2006, 691, 4802-4806.
(13) Gatard, S.; Çelenligil-Çetin, R.; Guo, C.; Foxman, B. M.; Ozerov, O. V. Carbon-Halide Oxidative Addition and Carbon-Carbon Reductive Elimination at a (PNP)Rh Center, J. Am. Chem. Soc. 2006, 128, 2808-2809.
(12) Weng, W.; Guo, C.; Çelenligil-Çetin, R.; Foxman, B. M.; Ozerov, O. V. Skeletal Change In The PNP Pincer Ligand Leads To A Highly Regioselective Alkyne Dimerization Catalyst, Chem. Commun. 2006, 197-199.
2005
(11) Fan. L.; Parkin, S.; Ozerov, O. V. Halobenzenes and Ir(I): Kinetic C-H Oxidative Addition and Thermodynamic C-Hal Oxidative Addition, J. Am. Chem. Soc. 2005, 127, 16772-16773.
(10) Fan, L.; Ozerov, O. V. Efficient Nickel Catalyst For Coupling Of Acetonitrile With Aldehydes Chem. Commun. 2005, 4450-4452.
(9) Weng, W.: Guo, C.; Moura, C. P.; Yang, L.; Foxman, B. M.; Ozerov, O. V. Competitive Activation of N-C and C-H Bonds of the PNP Framework by Monovalent Rhodium and Iridium, Organometallics 2005, 24, 3487-3499.
(8) Scott, V. J.; Çelenligil-Çetin, R.; Ozerov, O. V. Room-Temperature Catalytic Hydrodefluorination of Aliphatic C-F Bonds, J. Am. Chem. Soc. 2005, 127, 2852-2853. (See a highlight in the March 14th, 2005 issue of Chemical and Engineering News 2005, 83(11), 33.)
(7) Bailey, B. C.; Huffman, J. C.; Mindiola, D. J.; Weng, W.; Ozerov, O. V. Remarkably Stable Titanium Complexes Containing Terminal Alkylidene, Phosphinidene and Imide Functionalities, Organometallics 2005, 24, 1390-1393.
(6) Çelenligil-Çetin, R.; Watson, L. A.; Guo, C.; Foxman, B. M.; Ozerov, O. V. Decarbonylation of Acetone and Carbonate at a Pincer-Ligated Ru Center, Organometallics 2005, 24, 186-189.
2004
(5) Weng, W.; Yang, L.; Foxman, B. M.; Ozerov, O. V. Chelate-Enforced Phosphine Coordination Enables a-Abstraction to Give Zirconium Alkylidenes, Organometallics 2004, 23, 4700-4705.
(4) Ozerov, O. V.; Guo, C.; Fan. L.; Foxman, B. M. Oxidative Addition of N-C and N-H Bonds to Zero-Valent Nickel, Palladium, and Platinum, Organometallics 2004, 23, 5573-5580.
(3) Fan, L.; Yang, L.; Guo, C.; Foxman, B. M.; Ozerov, O. V. N-C Cleavage in Pincer PNP Complexes of Palladium, Organometallics 2004, 23, 4778-4787.
(2) Ozerov, O. V.; Guo, C.; Papkov, V. A.; Foxman, B. M. Facile Oxidative Addition of N-C and N-H Bonds to Monovalent Rhodium and Iridium, J. Am. Chem. Soc. 2004, 126, 4792-4793.
(1) Fan, L.; Foxman, B. M.; Ozerov, O. V. N-H Cleavage as a Route to Palladium Complexes of a New PNP Pincer Ligand, Organometallics 2004, 23, 326-328.
Prior Publications
From postdoctoral work at Indiana University
(9) Ozerov, O. V.; Watson, L. A.; Pink, M.; Caulton, K. G. Operationally Unsaturated Pincer/Rhenium Complexes Form Metal Carbenes from Cycloalkenes and Metal Carbynes from Alkanes, J. Am. Chem. Soc. 2007, 129, 6003-6016.
(8) Ozerov, O. V.; Watson, L. A.; Pink, M.; Baik, M.-H.; Caulton, K. G. Terminal Acetylenes React to Increase Unsaturation in [(tBu2PCH2SiMe2)2N]Re(H)4, Organometallics 2004, 23, 4934-4943.
(7) Ozerov, O. V.; Watson, L. A.; Pink, M.; Caulton, K. G. Transformation of Acyclic Alkenes to Hydrido Carbynes by (PNPR)Re Complexes, J. Am. Chem. Soc. 2004, 126, 6363-6378.
(6) Ozerov, O. V.; Pink, M.; Watson, L. A.; Caulton, K. G. Aromatic vs. Aliphatic C-H Cleavage of alkyl-Substituted Pyridines By (PNPiPr)Re Compounds, J. Am. Chem. Soc. 2004, 126, 2105-2113.
(5) Ozerov, O. V.; Huffman, J. C.; Watson, L. A.; Caulton, K. G. Conversion of Ethylene to Hydride and Ethylidyne by an Amido Rhenium Polyhydride, Organometallics 2003, 22, 2539-2541.
(4) Ozerov, O. V.; Watson, L. A.; Pink, M.; Caulton, K. G. A π-basic Rhenium Center that Effects Cyclohexene Isomerization to a β-Agostic Carbene Ligand, J. Am. Chem. Soc. 2003, 125, 9604-9605.
(3) Watson, L. A.; Ozerov, O. V.; Pink, M.; Caulton, K. G. Four-coordinate, Planar Ru(II). A Triplet State as a Response to 14 Valence Electron Configuration, J. Am. Chem. Soc. 2003, 125, 8426-8427.
(2) Watson, L. A.; Coalter, J. N. III; Ozerov, O. V.; Pink, M.; Huffman, J. C.; Caulton, K. G. Amido/phosphine pincer hydrides of ruthenium, New J. Chem. 2003, 27, 263-273.
(1) Ozerov, O. V.; Gerard, H. F.; Watson, L. A.; Huffman, J. C.; Caulton, K. G. Double Silyl Migration Converting ORe[(NSiMe2CH2PCy2)2] to NRe[(OSiMe2CH2PCy2)2] Substructures, Inorg. Chem. 2002, 41, 5615-5625.
From graduate work at University of Kentucky
(6) Kingston, J. V.; Ozerov, O. V.; Parkin, S. Brock, C. P.; Ladipo, F. T. Mechanistic Insight into Fragmentation Reactions of Titanapinacolate Complexes J. Am. Chem. Soc. 2002, 124, 12217-12224.
(5) Ozerov, O. V.; Brock, C. P.; Carr, S.; Parkin, S.; Ladipo, F. T. Unusual Reductive Coupling of Alkynes and Ketones: Reactivity of Titanacycles Supported by Dimethylsilylcalix[4]arene (DMSC) Ligand, Organometallics 2000, 19, 5016-5025.
(4) Ozerov, O. V.; Parkin, S.; Brock, C. P.; Ladipo, F. T. Reactivity of a Well-Characterized Titananorbornadiene(η6-arene) Complex with Ketones and Aldehydes, Organometallics 2000, 19, 4187-4190.
(3) Ozerov, O. V.; Patrick, B. O.; Ladipo, F. T. Highly Regioselective [2 + 2 + 2] Cycloaddition of Terminal Alkynes Catalyzed by η6-Arene Complexes of Titanium Supported by Dimethylsilyl-Bridged p-tert-Butyl Calix[4]arene Ligand, J. Am. Chem. Soc. 2000, 122, 6423-6431.
(2) Ozerov, O. V.; Ladipo, F. T.; Patrick, B. O. Highly Regioselective Alkyne Cyclotrimerization Catalyzed by Titanium Complexes Supported by Proximally Bridged p-tert-Butylcalix[4]arene Ligands, J. Am. Chem. Soc. 1999, 121, 7941-7942.
(1) Ozerov, O. V.; Ladipo, F. T.; Rath, N. P. Synthesis, Characterization, and Reactivity of Titanium(IV) Complexes Supported by Proximally Bridged p-tert-Butylcalix[4]arene Ligands, J. Organomet. Chem. 1999, 586, 223-233.